Ok here are my reports, thanks for the followup!
Excerpt from storage.cfg...
lvmthin: hdd-1
thinpool hdd-1
vgname hdd-1
content rootdir,images
nodes neptune
lvmthin: hdd-2
thinpool hdd-2
vgname hdd-2
content rootdir,images
nodes neptune
Not sure what to look for in journalctl, but I believe these disks are sdc and sdc, so picking up some errors from there...
Feb 09 07:35:01 neptune smartd[1751]: Device: /dev/sdc [SAT], 56 Currently unreadable (pending) sectors
Feb 09 07:35:01 neptune smartd[1751]: Device: /dev/sdc [SAT], 56 Offline uncorrectable sectors
Feb 09 07:35:01 neptune smartd[1751]: Device: /dev/sdc [SAT], SMART Prefailure Attribute: 1 Raw_Read_Error_Rate changed from 82 to 77
...
Feb 09 07:35:20 neptune pvestatd[2599]: activating LV 'hdd-1/hdd-1' failed: Activation of logical volume hdd-1/hdd-1 is prohibited while logical volume>
Feb 09 07:35:21 neptune pve-guests[2904]: activating LV 'hdd-2/hdd-2' failed: Activation of logical volume hdd-2/hdd-2 is prohibited while logical volu>
Feb 09 07:35:21 neptune pvesh[2674]: Starting VM 204 failed: activating LV 'hdd-2/hdd-2' failed: Activation of logical volume hdd-2/hdd-2 is prohibited>
Feb 09 07:35:21 neptune pvesh[2674]: Starting VM 407
Feb 09 07:35:21 neptune pve-guests[2677]: <root@pam> starting task UPID:neptune:00000BD5:000066DD:65C61C09:qmstart:407:root@pam:
Feb 09 07:35:21 neptune pve-guests[3029]: start VM 407: UPID:neptune:00000BD5:000066DD:65C61C09:qmstart:407:root@pam:
Feb 09 07:35:21 neptune pvestatd[2599]: activating LV 'hdd-2/hdd-2' failed: Activation of logical volume hdd-2/hdd-2 is prohibited while logical volume>
Feb 09 07:35:21 neptune pvestatd[2599]: status update time (11.545 seconds)
Feb 09 07:35:21 neptune systemd[1]: Started 407.scope.
...
Feb 09 07:35:22 neptune pvestatd[2599]: activating LV 'hdd-2/hdd-2' failed: Activation of logical volume hdd-2/hdd-2 is prohibited while logical volume>
Feb 09 07:35:23 neptune pvestatd[2599]: activating LV 'hdd-1/hdd-1' failed: Activation of logical volume hdd-1/hdd-1 is prohibited while logical volume>
...
Feb 09 07:35:35 neptune pvestatd[2599]: activating LV 'hdd-1/hdd-1' failed: Activation of logical volume hdd-1/hdd-1 is prohibited while logical volume>
Feb 09 07:35:35 neptune pvestatd[2599]: activating LV 'hdd-2/hdd-2' failed: Activation of logical volume hdd-2/hdd-2 is prohibited while logical volume>
Feb 09 07:35:35 neptune pve-guests[3755]: activating LV 'hdd-2/hdd-2' failed: Activation of logical volume hdd-2/hdd-2 is prohibited while logical volu>
And more of the same...
Others:
root@neptune:~# lvs
LV VG Attr LSize Pool Origin Data% Meta% Move Log Cpy%Sync Convert
hdd-1 hdd-1 twi-aotz-- 3.61t 52.54 6.34
hdd-1_meta0 hdd-1 -wi------- 0.02t
hdd-2 hdd-2 twi-aotz-- 3.61t 25.37 1.93