There is not enough information in your post.
https://landoflinux.com/linux_lvm_command_examples.html
The output of first 5 commands listed in above article will shine some light on what you have. Make sure to encode them in CODE tags.
The configuration of the VM will also be helpful, ie "qm config 100". Your statement of assigning "100 MB" doesnt sound correct, thats an extremely small capacity for almost anything in 2023.
Good luck
Blockbridge : Ultra low latency all-NVME shared storage for Proxmox - https://www.blockbridge.com/proxmox
		 
i follow steps in youtube in the create the windows VM.
thank you. below are the info.hope it helps
root@pveprodtemp:~# pvs
  PV         VG  Fmt  Attr PSize    PFree
  /dev/sdb3  pve lvm2 a--  <222.00g <16.00g
root@pveprodtemp:~# pvdisplay
  --- Physical volume ---
  PV Name               /dev/sdb3
  VG Name               pve
  PV Size               <222.00 GiB / not usable 2.98 MiB
  Allocatable           yes
  PE Size               4.00 MiB
  Total PE              56831
  Free PE               4095
  Allocated PE          52736
  PV UUID               quyux9-tYXf-jv0P-7LRt-bM6U-4Gue-lXJrZt
root@pveprodtemp:~# vgs
  VG  #PV #LV #SN Attr   VSize    VFree
  pve   1  11   0 wz--n- <222.00g <16.00g
root@pveprodtemp:~# vgdisplay pve
  --- Volume group ---
  VG Name               pve
  System ID
  Format                lvm2
  Metadata Areas        1
  Metadata Sequence No  59
  VG Access             read/write
  VG Status             resizable
  MAX LV                0
  Cur LV                11
  Open LV               8
  Max PV                0
  Cur PV                1
  Act PV                1
  VG Size               <222.00 GiB
  PE Size               4.00 MiB
  Total PE              56831
  Alloc PE / Size       52736 / 206.00 GiB
  Free  PE / Size       4095 / <16.00 GiB
  VG UUID               45RIAd-Y0Mo-9AjB-YTwR-nf5u-Gx3f-tCILdP
root@pveprodtemp:~# lvs
  LV            VG  Attr       LSize   Pool Origin Data%  Meta%  Move Log Cpy%Sync Convert
  data          pve twi-aotzD- 129.84g             100.00 4.18
  root          pve -wi-ao----  65.50g
  swap          pve -wi-ao----   8.00g
  vm-105-disk-0 pve Vwi-a-tz--  32.00g data        96.30
  vm-108-disk-0 pve Vwi-a-tz--  32.00g data        96.31
  vm-109-disk-0 pve Vwi-aotz--   4.00m data        14.06
  vm-109-disk-1 pve Vwi-aotz-- 200.00g data        22.89
  vm-109-disk-2 pve Vwi-aotz--   4.00m data        1.56
  vm-110-disk-0 pve Vwi-aotz--   4.00m data        14.06
  vm-110-disk-1 pve Vwi-aotz-- 100.00g data        22.42
  vm-110-disk-2 pve Vwi-aotz--   4.00m data        1.56
root@pveprodtemp:~# lvdisplay
  --- Logical volume ---
  LV Path                /dev/pve/swap
  LV Name                swap
  VG Name                pve
  LV UUID                t0rWIq-RoUP-2D3r-Oibl-vUX0-4qaB-rFWwAJ
  LV Write Access        read/write
  LV Creation host, time proxmox, 2023-05-06 03:28:23 +0800
  LV Status              available
  # open                 2
  LV Size                8.00 GiB
  Current LE             2048
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:0
  --- Logical volume ---
  LV Path                /dev/pve/root
  LV Name                root
  VG Name                pve
  LV UUID                g4dPl4-IECT-2WZC-9g2k-eYzI-Scgo-SBPWsj
  LV Write Access        read/write
  LV Creation host, time proxmox, 2023-05-06 03:28:24 +0800
  LV Status              available
  # open                 1
  LV Size                65.50 GiB
  Current LE             16768
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:1
  --- Logical volume ---
  LV Name                data
  VG Name                pve
  LV UUID                2VKo7g-1bct-955J-5Gpw-D9BH-WBYT-Rri5Ab
  LV Write Access        read/write (activated read only)
  LV Creation host, time proxmox, 2023-05-06 03:28:35 +0800
  LV Pool metadata       data_tmeta
  LV Pool data           data_tdata
  LV Status              available
  # open                 0
  LV Size                129.84 GiB
  Allocated pool data    100.00%
  Allocated metadata     4.18%
  Current LE             33240
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:5
  --- Logical volume ---
  LV Path                /dev/pve/vm-105-disk-0
  LV Name                vm-105-disk-0
  VG Name                pve
  LV UUID                AXq69d-bWhs-hu0q-fM63-VcjU-0VHR-9isxX8
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-05-09 22:39:32 +0800
  LV Pool name           data
  LV Status              available
  # open                 0
  LV Size                32.00 GiB
  Mapped size            96.30%
  Current LE             8192
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:6
  --- Logical volume ---
  LV Path                /dev/pve/vm-108-disk-0
  LV Name                vm-108-disk-0
  VG Name                pve
  LV UUID                e07KTq-b1E0-Cg4T-uICt-L5Nm-JcT1-O151fR
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-05-09 23:17:52 +0800
  LV Pool name           data
  LV Status              available
  # open                 0
  LV Size                32.00 GiB
  Mapped size            96.31%
  Current LE             8192
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:7
  --- Logical volume ---
  LV Path                /dev/pve/vm-109-disk-0
  LV Name                vm-109-disk-0
  VG Name                pve
  LV UUID                MHzXjm-pRDQ-GxWX-xm4H-wE3G-on0y-le5UIV
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-11-22 11:27:16 +0800
  LV Pool name           data
  LV Status              available
  # open                 1
  LV Size                4.00 MiB
  Mapped size            14.06%
  Current LE             1
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:8
  --- Logical volume ---
  LV Path                /dev/pve/vm-109-disk-1
  LV Name                vm-109-disk-1
  VG Name                pve
  LV UUID                kgclvf-hfwp-0VSN-FFDe-HOu0-oAkn-hj90F1
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-11-22 11:27:18 +0800
  LV Pool name           data
  LV Status              available
  # open                 1
  LV Size                200.00 GiB
  Mapped size            22.89%
  Current LE             51200
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:9
  --- Logical volume ---
  LV Path                /dev/pve/vm-109-disk-2
  LV Name                vm-109-disk-2
  VG Name                pve
  LV UUID                xRlpf6-v9dG-qoUP-eKI8-bh6c-Mmfu-SE3OWM
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-11-22 11:27:18 +0800
  LV Pool name           data
  LV Status              available
  # open                 1
  LV Size                4.00 MiB
  Mapped size            1.56%
  Current LE             1
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:10
  --- Logical volume ---
  LV Path                /dev/pve/vm-110-disk-0
  LV Name                vm-110-disk-0
  VG Name                pve
  LV UUID                VtQ37D-ZAGo-4Ffv-wMa4-YaCJ-4dSD-NOHiNY
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-11-23 15:50:41 +0800
  LV Pool name           data
  LV Status              available
  # open                 1
  LV Size                4.00 MiB
  Mapped size            14.06%
  Current LE             1
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:11
  --- Logical volume ---
  LV Path                /dev/pve/vm-110-disk-1
  LV Name                vm-110-disk-1
  VG Name                pve
  LV UUID                1tev3a-M5lX-gmqU-MspQ-G1Xr-79Q8-JKstOI
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-11-23 15:50:42 +0800
  LV Pool name           data
  LV Status              available
  # open                 1
  LV Size                100.00 GiB
  Mapped size            22.42%
  Current LE             25600
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:12
  --- Logical volume ---
  LV Path                /dev/pve/vm-110-disk-2
  LV Name                vm-110-disk-2
  VG Name                pve
  LV UUID                8AUBCG-uzcg-se64-5q6e-u2VD-cCQ2-8HqjDP
  LV Write Access        read/write
  LV Creation host, time pveprodtemp, 2023-11-23 15:50:43 +0800
  LV Pool name           data
  LV Status              available
  # open                 1
  LV Size                4.00 MiB
  Mapped size            1.56%
  Current LE             1
  Segments               1
  Allocation             inherit
  Read ahead sectors     auto
  - currently set to     256
  Block device           253:13
root@pveprodtemp:~#