This has been discussed on the forum more than a few times.
Best practices for one storage vendor will differ from another. This is best asked of your storage vendor.
If you extend, you will continue with single PVE storage pool. You'd be able to extend the LVs onto new space. You will not gain any performance benefit.
If you create a new VG that translates to new PVE storage pool. Potentially more flexibility and isolation.
Thats not strictly correct. You could/can extend a Datastore by concatenating LUNs.
May be. Depends what you meant by "treated individually". New Datastore - yes, VVOLs - no.
Without knowing detailed information about your environment, goals, etc - its hard to recommend any particular approach.
That said, most people will be content with one FC LUN which is as large as their storage allows and single PVE storage pool.
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