Thanks, here is the output scrubbed.
root@pve-05:~# cat /etc/pve/notifications.cfg
sendmail: mail-to-root
comment Send mails to root@pam's email address
disable true
mailto-user root@pam
matcher: default-matcher
comment Route all notifications to mail-to-root
disable true
mode all
target smtp-domain-com
smtp: smtp-domain-com
comment Send emails through internal exchange server
from-address
Proxmox@domain.com
mailto
Username@domain.com
mailto-user
Username2@domain.com
mode insecure
port 25
server 192.168.1.5
matcher: Exchange-matcher
comment Route all emails to smtp-domain-com
mode all
target smtp-domain-com
root@pve-05:~# cat /etc/pve/priv/notifications.cfg
smtp: smtp-domain-com
root@pve-05:~# postqueue -p
-Queue ID- --Size-- ----Arrival Time---- -Sender/Recipient-------
B6F49541216* 2603 Fri Sep 11 00:00:01
root@pve-05.domain.com
username@domain.com
13BD954104C 2603 Thu Sep 10 00:00:08
root@pve-05.domain.com
(conversation with mxb-0030cd01.gslb.pphosted.com[148.163.147.47] timed out while sending MAIL FROM)
username@domain.com
E9BC5541221 2603 Mon Sep 14 00:00:04
root@pve-05.domain.com
(conversation with mxb-0030cd01.gslb.pphosted.com[148.163.155.250] timed out while sending MAIL FROM)
username@domain.com
-- 7 Kbytes in 3 Requests.