Sure.
First you need to create a dataset on your PVE Host and mount it somewhere.
Here is an example:
	
	
	
		Code:
	
	
		root@proxmox:~# zfs list
NAME                      USED  AVAIL  REFER  MOUNTPOINT
HDD_Z2                   21.5T  82.2T   114K  /HDD_Z2
HDD_Z2/PVE_Backup         696G  82.2T   696G  /PVE_Backup
HDD_Z2/SMB_Data           125G  82.2T   125G  /smb/Data
HDD_Z2/SMB_Downloads      776G  82.2T   776G  /smb/Downloads
HDD_Z2/SMB_Media         18.8T  82.2T  18.8T  /smb/Media
HDD_Z2/SMB_Other         1.11T  82.2T  1.11T  /smb/Other
HDD_Z2/SMB_Rechnungen     235M  82.2T   235M  /smb/Rechnungen
	 
 
Second you need to passthrough that dataset to your LXC Container, i simply use the mounted location of that dataset and edit my LXC container Config, because thats not possible in the GUI for whatever reason....
Here is my Example Config:
	
	
	
		Code:
	
	
		arch: amd64
cores: 2
features: nesting=1
hostname: linux-srv
memory: 2048
mp0: /smb/Other,mp=/smb_storage/Other,replicate=0
mp1: /smb/Media,mp=/smb_storage/Media,replicate=0
mp2: /smb/Data,mp=/smb_storage/Data,replicate=0
mp3: /smb/Rechnungen,mp=/smb_storage/Rechnungen,replicate=0
mp4: /smb/Downloads,mp=/smb_storage/Downloads,replicate=0
net0: name=eth0,bridge=vmbr0,hwaddr=50:6D:FF:F3:C8:DD,ip=dhcp,ip6=auto,type=veth
onboot: 1
ostype: ubuntu
rootfs: NVME_ZFS_R10:subvol-103-disk-1,mountoptions=noatime,size=16G
startup: order=3
swap: 512
lxc.cap.drop:
lxc.cap.drop: mac_admin mac_override sys_module sys_rawio
	 
 
Only the mpX are important....
replicate=0 ist pretty important, to not Backup those Volumes with PBS...
Depending from the LXC Container if it Priviliged or Unpriviliged, you need to change the Rights on your PVE Host on the dataset mountpoint (to the UID:GID of the root user in the LXC Container).
But you need that only on a unpriviliged container, so you can skip that, because to run samba alone inside LXC you need a Priviliged Container as far i remember.
To find out the UID:GID of the Container:
Simply chmod the mountpoint from your dataset to 777 on the proxmox host, then enter your lxc container as root and create a file with nano or whatever on the mounted storage....
Then simply check on the proxmox host again with what UID:GID the file was created.... and chown the whole mountpoint to that...
And surely change back 777 to anything normal, like 775.
Then install on your Proxmox host anything that does the snapshots for you on your datasets...
I think in the meantime this is even implemented in Proxmox already...
However, im using still 
https://github.com/wezm/zfs-autosnap
Because i come from a time, where autosnapshots werent implemented in Proxmox....
Configure them....
then you have to configure smb.conf in your LXC container, one of my VSS Shares looks like this:
	
	
	
		Code:
	
	
		[Data]
   comment = Server Data
   path = /smb_storage/Data
   guest ok = no
   browseable = yes
   valid users = mw, root
   write list = mw, root
   create mask = 0775
   force create mode = 0775
   force user = samba
   force group = sambagroup
   vfs objects = shadow_copy2
   shadow:snapdir = /smb_storage/Data/.zfs/snapshot
   shadow:basedir = /smb_storage/Data
   shadow:sort = desc
   shadow:format = %Y-%m-%dT%H:%M:%SZ-autosnap
	 
 
but you will probably change that a little, to a format and directory that matches your snapshotting method.
Thats a super Cheap How-To, but should help you at least, or give you the right direction....
Cheers