This has been on ongoing problem for me for more than a year now, on numerous VM's - Windows and Linux Guests. Some running with virtio, some running in sata mode. This occurs if the backup mode is Snapshot and in Stop mode. When is it going to be fixed? I only run daily backups, never twice on the same day, but daily at least one of my VM backups will fail. Not always the same one in consecutive days, sometimes the same one 3 days in a row - no consistency with the failures.
vzdump 102 --node node1 --mode stop --storage qnap-2bay-nas-vmbackups --mailnotification failure --mailto
my@emailaddress.com --quiet 1 --compress lzo
102: 2019-06-25 22:30:02 INFO: Starting Backup of VM 102 (qemu)
102: 2019-06-25 22:30:02 INFO: status = running
102: 2019-06-25 22:30:03 INFO: update VM 102: -lock backup
102: 2019-06-25 22:30:03 INFO: backup mode: stop
102: 2019-06-25 22:30:03 INFO: ionice priority: 7
102: 2019-06-25 22:30:03 INFO: VM Name: BlueBox1.5
102: 2019-06-25 22:30:03 INFO: include disk 'sata0' 'ssdpool:vm-102-disk-1' 165G
102: 2019-06-25 22:30:03 INFO: stopping vm
102: 2019-06-25 22:30:19 INFO: creating archive '/mnt/pve/qnap-2bay-nas-vmbackups/dump/vzdump-qemu-102-2019_06_25-22_30_02.vma.lzo'
102: 2019-06-25 22:30:19 INFO: starting kvm to execute backup task
102: 2019-06-25 22:30:20 INFO: restarting vm
102: 2019-06-25 22:30:22 INFO: guest is online again after 19 seconds
102: 2019-06-25 22:30:22 ERROR: Backup of VM 102 failed - start failed: org.freedesktop.systemd1.UnitExists: Unit 102.scope already exists.
vzdump 103 --node node1 --mailnotification failure --compress lzo --mailto
my@emailaddress.com --storage qnap-2bay-nas-vmbackups --quiet 1 --mode stop
103: 2019-06-24 18:00:02 INFO: Starting Backup of VM 103 (qemu)
103: 2019-06-24 18:00:02 INFO: status = running
103: 2019-06-24 18:00:03 INFO: update VM 103: -lock backup
103: 2019-06-24 18:00:03 INFO: backup mode: stop
103: 2019-06-24 18:00:03 INFO: ionice priority: 7
103: 2019-06-24 18:00:03 INFO: VM Name: Vault
103: 2019-06-24 18:00:03 INFO: include disk 'virtio0' 'saspool:vm-103-disk-0' 300G
103: 2019-06-24 18:00:03 INFO: stopping vm
103: 2019-06-24 18:00:35 INFO: creating archive '/mnt/pve/qnap-2bay-nas-vmbackups/dump/vzdump-qemu-103-2019_06_24-18_00_01.vma.lzo'
103: 2019-06-24 18:00:35 INFO: starting kvm to execute backup task
103: 2019-06-24 18:00:36 INFO: restarting vm
103: 2019-06-24 18:00:38 INFO: guest is online again after 35 seconds
103: 2019-06-24 18:00:38 ERROR: Backup of VM 103 failed - start failed: org.freedesktop.systemd1.UnitExists: Unit 103.scope already exists.
root@node1:~# pveversion -v
proxmox-ve: 5.4-1 (running kernel: 4.15.18-14-pve)
pve-manager: 5.4-6 (running version: 5.4-6/aa7856c5)
pve-kernel-4.15: 5.4-3
pve-kernel-4.15.18-15-pve: 4.15.18-40
pve-kernel-4.15.18-14-pve: 4.15.18-39
pve-kernel-4.15.18-13-pve: 4.15.18-37
pve-kernel-4.15.18-12-pve: 4.15.18-36
pve-kernel-4.15.18-11-pve: 4.15.18-34
pve-kernel-4.15.18-10-pve: 4.15.18-32
pve-kernel-4.15.18-9-pve: 4.15.18-30
pve-kernel-4.15.18-7-pve: 4.15.18-27
pve-kernel-4.15.18-5-pve: 4.15.18-24
pve-kernel-4.15.18-4-pve: 4.15.18-23
pve-kernel-4.15.18-1-pve: 4.15.18-19
pve-kernel-4.15.17-2-pve: 4.15.17-10
pve-kernel-4.15.17-1-pve: 4.15.17-9
corosync: 2.4.4-pve1
criu: 2.11.1-1~bpo90
glusterfs-client: 3.8.15-1
ksm-control-daemon: 1.2-2
libjs-extjs: 6.0.1-2
libpve-access-control: 5.1-10
libpve-apiclient-perl: 2.0-5
libpve-common-perl: 5.0-52
libpve-guest-common-perl: 2.0-20
libpve-http-server-perl: 2.0-13
libpve-storage-perl: 5.0-43
libqb0: 1.0.3-1~bpo9
lvm2: 2.02.168-pve6
lxc-pve: 3.1.0-3
lxcfs: 3.0.3-pve1
novnc-pve: 1.0.0-3
proxmox-widget-toolkit: 1.0-28
pve-cluster: 5.0-37
pve-container: 2.0-39
pve-docs: 5.4-2
pve-edk2-firmware: 1.20190312-1
pve-firewall: 3.0-22
pve-firmware: 2.0-6
pve-ha-manager: 2.0-9
pve-i18n: 1.1-4
pve-libspice-server1: 0.14.1-2
pve-qemu-kvm: 3.0.1-2
pve-xtermjs: 3.12.0-1
qemu-server: 5.0-52
smartmontools: 6.5+svn4324-1
spiceterm: 3.0-5
vncterm: 1.5-3
zfsutils-linux: 0.7.13-pve1~bpo2