Raid1 is always safer, no matter if HDD or SSD. And should always be used for everything you care about. Including your NVMe SSDs for VM storage if you care about VM data-loss (even with backups you lose the data since your last backup) or not being able to access those VMs.
You will have to import/active/mount that disk via CLI and then add it as a storage in thre webUI at Datacenter -> Storage -> Add.
How to do that depends on how you formated your disk (ZFS, ext4, whatever).