and you will see the the exact KVM command that gets executed. Therefore, if you somehow get your VM working manually then you can compare the parameters of the processes.
root@prox:~# ps -aux | grep kvm
root 22080 8.6 12.9 4911852 4241736 ? Sl Feb11 98:16 /usr/bin/kvm -id 102 -name t2 -no-shutdown -chardev socket,id=qmp,path=/var/run/qemu-server/102.qmp,server,nowait -mon chardev=qmp,mode=control -chardev socket,id=qmp-event,path=/var/run/qmeventd.sock,reconnect=5 -mon chardev=qmp-event,mode=control -pidfile /var/run/qemu-server/102.pid -daemonize -smbios type=1,uuid=95963d08-898f-4afd-a92e-32732d308d23 -drive if=pflash,unit=0,format=raw,readonly,file=/usr/share/pve-edk2-firmware//OVMF_CODE.fd -drive if=pflash,unit=1,format=qcow2,id=drive-efidisk0,file=/mnt/hostrun/content/images/102/vm-102-disk-1.qcow2 -smp 2,sockets=1,cores=2,maxcpus=2 -nodefaults -boot menu=on,strict=on,reboot-timeout=1000,splash=/usr/share/qemu-server/bootsplash.jpg -vnc unix:/var/run/qemu-server/102.vnc,password -no-hpet -cpu kvm64,enforce,hv_ipi,hv_relaxed,hv_reset,hv_runtime,hv_spinlocks=0x1fff,hv_stimer,hv_synic,hv_time,hv_vapic,hv_vpindex,+kvm_pv_eoi,+kvm_pv_unhalt,+lahf_lm,+sep -m 4096 -device pci-bridge,id=pci.1,chassis_nr=1,bus=pci.0,addr=0x1e -device pci-bridge,id=pci.2,chassis_nr=2,bus=pci.0,addr=0x1f -device vmgenid,guid=7bf49d5b-bf15-45f2-98f9-941f99001aad -device piix3-usb-uhci,id=uhci,bus=pci.0,addr=0x1.0x2 -device usb-tablet,id=tablet,bus=uhci.0,port=1 -device VGA,id=vga,bus=pci.0,addr=0x2 -chardev socket,path=/var/run/qemu-server/102.qga,server,nowait,id=qga0 -device virtio-serial,id=qga0,bus=pci.0,addr=0x8 -device virtserialport,chardev=qga0,name=org.qemu.guest_agent.0 -device virtio-balloon-pci,id=balloon0,bus=pci.0,addr=0x3 -iscsi initiator-name=iqn.1993-08.org.debian:01:b44d438070d7 -drive file=/var/lib/vz/template/iso/en-ru_windows_10_enterprise_ltsb_2016_with_update_14393.4169_aio_2in1_x64_v21.01.12_by_adguard.iso,if=none,id=drive-ide2,media=cdrom,aio=threads -device ide-cd,bus=ide.1,unit=0,drive=drive-ide2,id=ide2,bootindex=100 -device ahci,id=ahci0,multifunction=on,bus=pci.0,addr=0x7 -drive file=/mnt/hostrun/content/images/102/win10_1607.qcow2,if=none,id=drive-sata0,format=qcow2,cache=none,aio=native,detect-zeroes=on -device ide-hd,bus=ahci0.0,drive=drive-sata0,id=sata0,bootindex=101 -netdev type=tap,id=net0,ifname=tap102i0,script=/var/lib/qemu-server/pve-bridge,downscript=/var/lib/qemu-server/pve-bridgedown -device e1000,mac=C2:CB
D:37:ED:E7,netdev=net0,bus=pci.0,addr=0x12,id=net0 -rtc driftfix=slew,base=localtime -machine type=pc+pve0 -global kvm-pit.lost_tick_policy=discard
root 22084 0.0 0.0 0 0 ? S Feb11 0:00 [kvm-nx-lpage-re]
root 22128 0.2 0.0 0 0 ? S Feb11 3:11 [kvm-pit/22080]
root 61719 0.0 0.0 6072 892 pts/0 S+ 11:08 0:00 grep kvm
root@prox:~#
Code:
boot: order=ide2;sata0;net0
ide2 is empty in your case.
ide2 is dvd-rom and it is disabled (empty)