Problem to add Proxmox Backup Server to Cluster

Since it's a network connection, check the firewall.

Then, the most common reason for "weird errors" like that is an error in the filesystem. Check with fsck for errors.
 
Is there a typo? /dev/sdb isn't a filesystem. Any way, you have to umount or run in single mode to check the filesystem.
 
@omgs thanks so far. On firewall side i can not find any issue. Ping and traceroute works fine, routing works also. do you mean fsck check on backup server or pve site?
Apart from basic connection, I meant the if the port is open for connection. Did you check that?