Thanks for the logs and command outputs.
So there seems to be an issue with the communication to the NFS share your VM/CT disks are located on, e.g. in the output of ps we can see that setting up the loop device is blocked in an uninterruptible sleep state. Therefore the startup never finishes.
As a first step, please make sure the NFS share is mounted correctly and reachable. Try booting without autostarting any guests and only start the guests after the storage is reachable. Check if that solves your issue.
So there seems to be an issue with the communication to the NFS share your VM/CT disks are located on, e.g. in the output of ps we can see that setting up the loop device is blocked in an uninterruptible sleep state. Therefore the startup never finishes.
Code:
root 96123 0.0 0.0 2796 1536 ? D 23:11 0:00 \_ losetup --show -f /mnt/pve/NFS-SYNO/images/103/vm-103-disk-0.raw
As a first step, please make sure the NFS share is mounted correctly and reachable. Try booting without autostarting any guests and only start the guests after the storage is reachable. Check if that solves your issue.