No, since the whitelist on mail-proxy level only disables the SPF-checks (this is independent of the scores SpamAssassin distributes for wrong SPF), postscreen checks (RBL lookups and protocol errors) and greylisting.
you can maybe use the Blacklist in the Rule-System - then all mail will get fed through it and then blacklisted there
why would you need a blacklist on mail-proxy level?
I hope this helps!