I am in need of adding some space on my ZFS pool and wanted to see if it was possible to add more disks to this or if I would only replace Existing drives with Larger ones.
Depends on your pool setup. Whats your output of zpool status? If its not a draid it should work. But if you also boot from that pool it gets a bit harder.
Do you want to expand Storage01 or rpool? Do you got two more 2.5" slots and SATA/SAS ports? Adding more disks to Storage1 should be easy. You could get another 2 SSDs and make that mirror to a striped mirror like your rpool. I think to rpool you also could add a new mirror but then you would need to manually partition and format the new disks first, copy/sync over the bootloader to the boot partition and only after that create a mirror using the two third partitions.