Thanks for your continued help. Here are the details you requested.
In advance, as an aside, this host machine is an Intel NUC ( Intel NUC - NUC8i5BEH ). It can ping peers, but just can route through default GW 192.168.178.30 -- my Unifi Dreammachine SE). I can ping my router (192.168.178.30) from other machines (Windows). NSLookup's work from proxmox host.
############################
# pveversion -v
proxmox-ve: 7.0-2 (running kernel: 5.11.22-4-pve)
pve-manager: 7.0-11 (running version: 7.0-11/63d82f4e)
pve-kernel-5.11: 7.0-7
pve-kernel-helper: 7.0-7
pve-kernel-5.11.22-4-pve: 5.11.22-8
ceph-fuse: 15.2.14-pve1
corosync: 3.1.2-pve2
criu: 3.15-1+pve-1
glusterfs-client: 9.2-1
ifupdown2: 3.1.0-1+pmx3
ksm-control-daemon: 1.4-1
libjs-extjs: 7.0.0-1
libknet1: 1.21-pve1
libproxmox-acme-perl: 1.3.0
libproxmox-backup-qemu0: 1.2.0-1
libpve-access-control: 7.0-4
libpve-apiclient-perl: 3.2-1
libpve-common-perl: 7.0-6
libpve-guest-common-perl: 4.0-2
libpve-http-server-perl: 4.0-2
libpve-storage-perl: 7.0-10
libspice-server1: 0.14.3-2.1
lvm2: 2.03.11-2.1
lxc-pve: 4.0.9-4
lxcfs: 4.0.8-pve2
novnc-pve: 1.2.0-3
proxmox-backup-client: 2.0.9-2
proxmox-backup-file-restore: 2.0.9-2
proxmox-mini-journalreader: 1.2-1
proxmox-widget-toolkit: 3.3-6
pve-cluster: 7.0-3
pve-container: 4.0-9
pve-docs: 7.0-5
pve-edk2-firmware: 3.20200531-1
pve-firewall: 4.2-2
pve-firmware: 3.3-1
pve-ha-manager: 3.3-1
pve-i18n: 2.5-1
pve-qemu-kvm: 6.0.0-3
pve-xtermjs: 4.12.0-1
qemu-server: 7.0-13
smartmontools: 7.2-1
spiceterm: 3.2-2
vncterm: 1.7-1
zfsutils-linux: 2.0.5-pve1
############################
# ip addr
1: lo: <LOOPBACK,UP,LOWER_UP> mtu 65536 qdisc noqueue state UNKNOWN group default qlen 1000
link/loopback 00:00:00:00:00:00 brd 00:00:00:00:00:00
inet 127.0.0.1/8 scope host lo
valid_lft forever preferred_lft forever
inet6 ::1/128 scope host
valid_lft forever preferred_lft forever
2: eno1: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast master vmbr0 state UP group default qlen 1000
link/ether 1c:69:7a:00:23:6c brd ff:ff:ff:ff:ff:ff
altname enp0s31f6
3: wlp0s20f3: <BROADCAST,MULTICAST> mtu 1500 qdisc noop state DOWN group default qlen 1000
link/ether d0:c6:37:27:63:cf brd ff:ff:ff:ff:ff:ff
4: vmbr0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue state UP group default qlen 1000
link/ether 1c:69:7a:00:23:6c brd ff:ff:ff:ff:ff:ff
inet 192.168.178.32/24 scope global vmbr0
valid_lft forever preferred_lft forever
inet6 fe80::1e69:7aff:fe00:236c/64 scope link
valid_lft forever preferred_lft forever
5: tap100i0: <BROADCAST,MULTICAST,PROMISC,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast master vmbr0 state UNKNOWN group default qlen 1000
link/ether e2:e7:cd:a2:c9:dd brd ff:ff:ff:ff:ff:ff
6: tap102i0: <BROADCAST,MULTICAST,PROMISC,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast master fwbr102i0 state UNKNOWN group default qlen 1000
link/ether aa:59:f4:37:9a:ce brd ff:ff:ff:ff:ff:ff
7: fwbr102i0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue state UP group default qlen 1000
link/ether de:d0:44:16:0f:4d brd ff:ff:ff:ff:ff:ff
8: fwpr102p0@fwln102i0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue master vmbr0 state UP group default qlen 1000
link/ether 4a:0a:ad:f8:5c:06 brd ff:ff:ff:ff:ff:ff
9: fwln102i0@fwpr102p0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue master fwbr102i0 state UP group default qlen 1000
link/ether 06:65:ca:b4:38:46 brd ff:ff:ff:ff:ff:ff
10: tap104i0: <BROADCAST,MULTICAST,PROMISC,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast master fwbr104i0 state UNKNOWN group default qlen 1000
link/ether 6e:62:a2:d2:63:b5 brd ff:ff:ff:ff:ff:ff
11: fwbr104i0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue state UP group default qlen 1000
link/ether 7e:29:93:9d:d8:11 brd ff:ff:ff:ff:ff:ff
12: fwpr104p0@fwln104i0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue master vmbr0 state UP group default qlen 1000
link/ether 2e:2c:77:a4:3b:22 brd ff:ff:ff:ff:ff:ff
13: fwln104i0@fwpr104p0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue master fwbr104i0 state UP group default qlen 1000
link/ether 42:33:2a:12:1b:c3 brd ff:ff:ff:ff:ff:ff
14: tap105i0: <BROADCAST,MULTICAST,PROMISC,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast master fwbr105i0 state UNKNOWN group default qlen 1000
link/ether 1a:b1:cf:5a:0a:0a brd ff:ff:ff:ff:ff:ff
15: fwbr105i0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue state UP group default qlen 1000
link/ether 32:f9:a5:55:f4:4c brd ff:ff:ff:ff:ff:ff
16: fwpr105p0@fwln105i0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue master vmbr0 state UP group default qlen 1000
link/ether 96:11:23:c3:20:be brd ff:ff:ff:ff:ff:ff
17: fwln105i0@fwpr105p0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc noqueue master fwbr105i0 state UP group default qlen 1000
link/ether 4e:c0:02:74:ee:b1 brd ff:ff:ff:ff:ff:ff
############################
# ip route
default via 192.168.178.30 dev vmbr0 proto kernel onlink
192.168.178.0/24 dev vmbr0 proto kernel scope link src 192.168.178.32
############################
# ip neigh show
192.168.178.94 dev vmbr0 lladdr de:e2:bb:5f:d6:ab STALE
192.168.178.30 dev vmbr0 lladdr d2:21:f9:89:7b:04 STALE
192.168.178.131 dev vmbr0 lladdr c4:9d:ed:91:36:6e DELAY
fe80::3abf:c4bc:cdf3:b504 dev vmbr0 lladdr c4:9d:ed:91:36:6e STALE
fe80::8d7:e15a:6fb4:4ea2 dev vmbr0 lladdr e6:ef:c6:f4:65:ed STALE
fe80::822b:f9ff:fe49:1431 dev vmbr0 lladdr 80:2b:f9:49:14:31 STALE
fe80::cbf1:470:585:d67f dev vmbr0 lladdr c8:34:8e:72:22:8f STALE
fe80::e469:8cff:fe03:d294 dev vmbr0 lladdr e6:69:8c:03:d2:94 STALE
fe80::446:c794:c6e1:171d dev vmbr0 lladdr 82:7b:e1:2b:1a:92 STALE
fe80::8810:e6ff:feb7:f326 dev vmbr0 lladdr 8a:10:e6:b7:f3:26 STALE
fe80::5ec5:63ff:fe26:be9f dev vmbr0 lladdr 5c:c5:63:26:be:9f STALE
fe80::dce2:bbff:fe5f:d6ab dev vmbr0 lladdr de:e2:bb:5f:d6:ab STALE
fe80::14a8:978b:592d:d90f dev vmbr0 lladdr a2:9b:50:e3:58:d7 STALE
fe80::1479:7b5e:7379:70ad dev vmbr0 lladdr ba:e8:83:85:a8:4c STALE
Thanks in Advance,
~Bryan