Notice sendgrid use CNAME for their emails services, you will encounter receiving issue if you enable reject_unknown_sender_domain.
You might want to whitelite the unknown domain under Configuration -> Mail Proxy -> whitelist.

You might want to whitelite the unknown domain under Configuration -> Mail Proxy -> whitelist.

Code:
Jun 4 12:37:14 pmg postfix/smtpd[27059]: connect from o1.em.autodeskcommunications.com[50.31.54.242]
Jun 4 12:38:24 pmg postfix/smtpd[27059]: NOQUEUE: reject: RCPT from o1.em.autodeskcommunications.com[50.31.54.242]: 450 4.1.8 <bounces+1595434-73df-xxx=xxx.com@em7210.autodesk.com>: Sender address rejected: Domain not found; from=<bounces+1595434-73df-xxx=xxx.com@em7210.autodesk.com> to=<xxx@xxx.com> proto=ESMTP helo=<o1.em.autodeskcommunications.com>
Jun 4 12:38:24 pmg postfix/smtpd[27059]: lost connection after RCPT from o1.em.autodeskcommunications.com[50.31.54.242]
Jun 4 12:38:24 pmg postfix/smtpd[27059]: disconnect from o1.em.autodeskcommunications.com[50.31.54.242] ehlo=1 mail=1 rcpt=0/1 commands=2/3
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