Hi,
why do you what to use OpenVswitch?
OpenVswitch is only for advances use for user how to know openVswitch.
All common network setups can be done with Linux bridges.
For this Linux Bridges work fine.So,I think,the OVS should be used.
Create a Bridge without a port and connect all VM "PFSense and VM" to it.Several pfsense firewalls connect to a switch, and Some PC connect to a pfsense.
You can capture it directly on the bridge or what you like do?port mirror
You can capture it directly on the bridge or what you like do?