Hello, you really should read about LVM and FS in Linux. In simple words you should create LVM on your second RAID and add it in Proxmox, OR create FS (like ext3) on the RAID, mount it and add to Proxmox. LVM more preferable because it allows you to create snapshots.
You could try this instruction http://blog.tugov.pro/2012/05/proxmoxve-2-raid1.html it's in Russian, but very simple. I've tried it today and it works smooth =) If you have any questions ask please.
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