I still have made some more Speed Tests, between the Tests I always rebooted, so that nothing is cached:
dd inside the Nas4Free VM (SATA Controller passed through):
nas4free: ~ # dd if=/mnt/raid1-ssd/pve/images/110/vm-110-disk-1.qcow2 of=/dev/null bs=2M count=3000
3000+0 records in
3000+0...