Shrinking a disk is an operation that can lead to much pain if done incorrectly...
You have not specified what type of disk you have and your definition of "empty" is not clear. Does it have a partition? filesystem? If it does - the filesystem knows about the disk size, things sometimes are written to the end of the disk for safekeeping.
PVE has no understanding of what data is on the disk : filesystem? another volume manager? something more complex?
Some of the above allow for underlying device to be shrunk, others do not. You must start with File System, sometimes continue with Partition, then perhaps a volume manager and only then, may be, a disk.
So this is an advanced operation that cant be executed with a click of a button.
And if the disk is empty why not just delete it and create the one you want?
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